Yeah, follow Luke's ideas. Getting it to pure white might be tough though. Any 'real' colour and you can just mask off the wall and apply AE's tint to it. Not sure how well that works for a changing a dark colour into white. Worth a try though.
If it doesn;t work so well then dupliate the layer, mask off the wall, desaturate it to get the wall to black of dark grey and then invert it.
Might help. Without more info that's all I have right now.
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